Oxidation of olefins to ketones catalyzed by a water-soluble palladium complex with calix[4]arene modified with benzonitrile groupsстатья
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Местоположение издательства:Road Town, United Kingdom
Первая страница:154
Последняя страница:158
Аннотация:The biphasic oxidation of some linear alkenes (from 1-hexene to 1-dodecene) and styrenes to ketones catalyzed by a water-soluble palladium(II) complex with a benzonitrile moiety-containing calixarene was studied in a substrate-water system. It was shown that the use of the complex substantially increases the activity of this catalyst system as compared with similar systems containing a palladium salt and water-soluble calixarene. The substrate selectivity of the catalyst was revealed, its maximum activity was achieved in the case of 1-heptene.