Chemical and electrochemical synthesis, structure and magnetic properties of mono- and binuclear 3d-metal complexes of N-[2-[(hydroxyalkylimino)methyl]phenyl]-4-methylbenzenesulfonamidesстатья
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Дата последнего поиска статьи во внешних источниках: 24 февраля 2021 г.
Аннотация:Complexes of Cu(II), Ni(II), Co(II) and Fe(II) ions with N-[2-[(hydroxyalkylimino)methyl]phenyl]-4-methylbenzenesulfonamides containing the (CH2)n-spacer of a variable length (n = 2–6) were synthesized by chemical and electrochemical methods. All the compounds were characterized by C, H and N elemental analysis, IR, EPR and X-ray absorption spectroscopy data. The dimeric structures of the copper complexes with (CH2)n-spacers (n = 2, 3) were determined by the magnetochemical method and by X-ray diffraction analysis for the copper complex with the (CH2)3-spacer.