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Small-Angle X-Ray Scattering Study of Polymer Structure: Carbosilane Dendrimers in Hexane Solutionстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 8 января 2017 г.
- Авторы: Shtykova E.V., Feigin L.A., Volkov V.V., Malakhova Yu N., Streltsov D.R., Buzin A.I., Chvalun S.N., Katarzhanova E.Yu, Ignatieva G.M., Muzafarov A.M.
- Журнал: Crystallography Reports
- Том: 61
- Номер: 5
- Год издания: 2016
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 815
- Последняя страница: 825
- DOI: 10.1134/S1063774516050199
- Аннотация: The three-dimensional organization of monodisperse hyper-branched macromolecules of regular structure—carbosilane dendrimers of zero, third, and sixth generations—has been studied by small-angle X-ray scattering (SAXS) in solution. The use of modern methods of SAXS data interpretation, including ab initio modeling, has made it possible to determine the internal architecture of the dendrimers in dependence of the generation number and the number of cyclosiloxane end groups (forming the shell of dendritic macromolecules) and show dendrimers to be spherical. The structural results give grounds to consider carbosilane dendrimers promising objects for forming crystals with subsequent structural analysis and determining their structure with high resolution, as well as for designing new materials to be used in various dendrimer-based technological applications.
- Добавил в систему: Штыкова Элеонора Владимировна