Mixed-Cation Molybdate Complex of Neptunium(V), Li2Na[NpO2(MoO4)2]·4H2Oстатья
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Дата последнего поиска статьи во внешних источниках: 24 ноября 2021 г.
Аннотация:A new mixed-cation complex Li2Na[NpO2(MoO4)2]·4H2O with NpO2+ : MoO42– = 1 : 2 has been synthesized and structurally characterized. The coordination environment of Np(V) atoms is a pentagonal bipyramidthe equatorial plane of which is formed by oxygen atoms of fi ve MoO42– anions. The structure is based on anionicneptunoyl-molybdate layers, with hydrated Li+ and Na+ cations bound via the common vertices of the coordinationpolyhedra into chains situated in the interlayer space.