Nonmonotonic Photostability of BA2MAn–1PbnI3n+1 Homologous Layered Perovskitesстатья
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Дата последнего поиска статьи во внешних источниках: 1 апреля 2022 г.
Аннотация:Layered lead halide perovskites (2D LHPs) are attracting considerable attention as a promising material for a new generation of solar cell devices. LHPs have been presented as a more stable alternative to the more widespread 3D bulk perovskite materials; however, a critical analysis of their photostability is still lacking. In this work, we perform a comparative study between BA2MAn–1PbnI3n+1 (BA─butylammonium and MA─methylammonium) 2D LHPs with different dimensionalities (n = 1–3) and MAPbI3 3D perovskites. We compare different stability testing protocols including photometrical determination of iodine-containing products in nonpolar solvents, X-ray diffraction, and photoluminescence (PL) spectroscopy. The resulting trends of the photostability in an inert atmosphere based on PL spectroscopy measurements demonstrate a nonmonotonic dependence of the degradation rate on the perovskite layer thickness n with a “stability island” at n ≥ 3, which is caused by a combination of antibate factors of electronic structures and chemical compositions in the family of 2D perovskites. We also identify a critical oxygen concentration in the surrounding environment that affects the mechanism and strongly enhances the rate of layered perovskite photodegradation.