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L-alanine/nickel-induced size-sorting of lanthanide(III) ions in 4f-4fꞌ heterometallic complexesстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 11 мая 2017 г.
- Авторы: Bezzubov S.I., Churakov Andrei V., Belousov Yuriy A., Bilyalova Alfiya A., Lavrova Maria A., Zharinova Irina S., Kiselev Yuri M., Dolzhenko Vladimir D.
- Журнал: Crystal Growth and Design
- Том: 17
- Номер: 3
- Год издания: 2017
- Издательство: American Chemical Society
- Местоположение издательства: United States
- Первая страница: 1166
- Последняя страница: 1172
- DOI: 10.1021/acs.cgd.6b01563
- Аннотация: A versatile approach to create the novel class of mixed-lanthanide compounds with predetermined location of different lanthanides in cationic and anionic positions has been developed. Pure 4f-4fꞌ heterometallic complexes were constructed from two independent building blocks: the complex cation [Ln{Ni(ala)2}6]3+ (ala = L-alaninate), which can be formed by La3+, Ce3+, Pr3+, and Nd3+ exclusively, and the anion [Gd(NO3)3(OH)3(H2O)]3−. The composition and structures of the com-plexes were studied by X-ray crystallography, EDX, and ICP-MS. The X-ray structural analysis showed the high rigidity of the L-alanine/Ni(II) supramolecular unit in the complex cations that affected immediately its selectivity towards certain lanthanides.
- Добавил в систему: Долженко Владимир Дмитриевич