Optical and electrochemical properties of novel fused tricyclic thiophene–15-crown-5 systems and their complexes with Mg and Ba ions

Tokarev, S.D.; Botezatu, A.; Khoroshutin, A.V.; Fedorov, Y.V.; Fedorova, O.A.

Информация о цитировании статьи получена из Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 20 июля 2022 г.

Авторы: Tokarev Sergey D., Botezatu Anatoly, Khoroshutin Andrey V., Fedorov Yury V., Fedorova Olga A.
Журнал: Mendeleev Communications
Том: 32
Год издания: 2022
Издательство: Elsevier BV
Местоположение издательства: Netherlands
Первая страница: 367
Последняя страница: 370
DOI: 10.1016/j.mencom.2022.05.025
Аннотация: New polycyclic aromatic derivatives annulated both with thiophene and with 15-crown-5 ether moieties, crown naphthothiophenes, were synthesized via the Mallory photocyclization with the use of iodine as the mild oxidizer, while two isomeric products were readily separated by column chromatography. Their complexation with Ba2+ and Mg2+ cations was examined by both optical and electrochemical methods. Spectroelectrochemical studies indicate that the obtained compounds, depending on their structure, can be chemically stable in the oxidized state.
Добавил в систему: Токарев Сергей Дмитриевич

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Optical and electrochemical properties of novel fused tricyclic thiophene–15-crown-5 systems and their complexes with Mg and Ba ionsстатья

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