Место издания:ELECTROCHEMICAL SOCIETY INC 65 S MAIN ST, PENNINGTON, NJ 08534-2839 USA
Первая страница:225
Последняя страница:238
Аннотация:Comparison studies of C(60) fluorination with solid binary (MeF(n)) or complex (M(k)MeF(n)) metal fluorides and with elemental fluorine under low-pressure conditions was conducted by means of electron impact mass spectrometry, using Knudsen cell as a reactor. All the reactions are accompanied by distillation of the volatile products C(60)F(2m). The results are discussed in the framework of the developed kinetic model, offering an explanation of the observed facts. The reasons and conditions for selectivity have been recognized.