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Exploring new belousovite-related zinc and cadmium alkali sulfate halides: synthesis and structural variabilityстатья
- Авторы: Borisov Artem S., Siidra Oleg I., Charkin Dmitri O., Zagidullin Karim A., Burshtynovich Ruslan K., Vlasenko Natalia S.
- Журнал: Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
- Том: 78
- Номер: 3
- Год издания: 2022
- Издательство: International Union of Crystallography
- Местоположение издательства: United Kingdom
- Первая страница: 499
- Последняя страница: 509
- DOI: 10.1107/s2052520622003535
- Аннотация: Fourteen new belousovite-related compounds, AZn(TO4)X (A = K, Rb, Cs, Tl, NH4; T = S, Se; X = Cl, Br, I) have been prepared via melt and evaporation techniques by reacting AX and ZnTO4 either at high temperatures or in hot aqueous solutions. They adopt the layered structure of the belousovite archetype, and constitute a morphotropic series. The apophyllite-type layers in these structures undergo different corrugations, most pronounced in the case of CsZn(SO4)I. In addition, during the study two species unrelated to belousovite, namely Na4Zn(SO4)2Cl2 and Cs2Cd3(SO4)4, were found with framework crystal structures having different topology and belonging to new structure types.
- Добавил в систему: Чаркин Дмитрий Олегович