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Organophotoredox-Catalyzed Reductive Tetrafluoroalkylation of Alkenesстатья
- Авторы: Kostromitin Vladislav S., Levin Vitalij V., Dilman Alexander D.
- Журнал: The journal of organic chemistry
- Год издания: 2022
- DOI: 10.1021/acs.joc.2c00712
- Аннотация: A method for the hydroperfluoroalkylation of alkenes with 1,2-dibromotetrafluoroethane leading to tetrafluorinated bromides is described. The reaction is conveniently performed under blue light irradiation using an organic photocatalyst and ascorbic acid as a reducing agent. Primary products can be further functionalized via radical pathways affording various tetrafluorinated compounds.
- Добавил в систему: Костромитин Владислав Сергеевич