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Spectral-luminescence properties of a norbornene-substituted tetraazachlorin and its metal complexesстатья
Информация о цитировании статьи получена из
Web of Science,
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 марта 2017 г.
- Авторы: Belkov M.V., Grishchuk A.A., Dudkin S.V., Makarova E.A., Pershukevich P.P., Solovyova K.N.
- Журнал: Journal of Applied Spectroscopy
- Том: 77
- Номер: 2
- Год издания: 2010
- Издательство: Springer-Verlag
- Местоположение издательства: Heidelberg, Germany
- Первая страница: 213
- Последняя страница: 222
- DOI: 10.1007/s10812-010-9317-5
- Аннотация: The spectral-luminescence properties of a tetraazachlorin derivative with a norbornene fragment annelated to a reduced pyrrole ring and its complexes with zinc and palladium have been studied at 293 and 77 K. For the norbornene-substituted free base, differences in fluorescence from unsubstituted tetraazachlroin and its dibenzobarrelene-substituted analog are found. The fluorescence lifetime is observed to rise by ~7 times for the free base and by ~1.6 ties for the Zn complex on going from 293 to 77 K. An essential dependence of the photophysical parameters on the nature of the solvent is noted. The fluorescence polarization spectrum of the norbornene-substituted tetraazachlorin reveals in the Soret band region at least four electronic transitions. For the Pd complex, weak phosphorescence in the near IR region has been detected; the 0–0 band maximum is at 990 nm and the singlet–triplet interval amounts to 5800 cm–1, which is larger by 400 cm–1 than for Pd tetraazaporphine. The quantum yields of the photosensitized formation of singlet oxygen have been determined using a relative luminescence method.
- Добавил в систему: Дудкин Семён Валентинович