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The higher chlorofullerene, D3d-C60Cl30, and its dioxide, C2h-C60Cl30O2статья
- Автор: Troyanov S.I.
- Журнал: Inorganica Chimica Acta
- Том: 544
- Год издания: 2023
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Номер статьи: 121240
- DOI: 10.1016/j.ica.2022.121240
- Аннотация: The highest chloride of the Isolated-Pentagon Rule (IPR) fullerene C60, D3d-C60Cl30 was isolated as solvates with toluene, o-dichlorobenzene, tetrachloroethane, and SbCl5. An X-ray crystallographic study of the solvates revealed a high rigidity of the D3d-C60Cl30 molecule due to the existence of isolated aromatic systems, two isolated benzenoid rings and one 18 trannulene ring. In two 15-membered chlorinated loops, ClCCCl distances are elongated to 1.58 – 1.69 Å. An X-ray diffraction study of the oxidation product, C60Cl30O2, showed that the addition of both oxygen atoms occurs by an insertion into the weakest ClCCCl bond under formation of intramolecular diether. In the C2h-C60Cl30O2 molecule, the ClCCCl distances of the cleaved CC bonds are 2.43 Å long whereas the aromatic system remains nearly untouched.
- Добавил в систему: Троянов Сергей Игоревич
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | Полный текст | proof | Proof.pdf | 736,9 КБ | 10 октября 2022 [Troyanov] |
| 2. | paper_acceptance | Paper_acceptance.docx | 44,0 КБ | 10 октября 2022 [Troyanov] |