Boron-Cluster Embedded Necklace-Shaped Nanohoops

Авторы: Miao Zhu, Zhou Qin, Cheng He, Sha Ye, Bregadze Vladimir I., Yan Hong, Sun Zhe, Li Xiang
Журнал: Angewandte Chemie - International Edition
Том: 62
Номер: 1
Год издания: 2023
Издательство: John Wiley & Sons Ltd.
Местоположение издательства: United Kingdom
Номер статьи: e202213470
DOI: 10.1002/anie.202213470
Аннотация: The combination of carbon-based nanohoops with other functional organic molecular structures should lead to the design of new molecular configurations with interesting properties. Here, the necklace nanohoops embedded with carborane were synthesized for the first time. The unique deboronization of o-carborane has led to facile preparation of ionic nanohoop compounds. Nanohoops functionalized by nido-o-carborane show excellent fluorescence emission properties, with a solution quantum yield up to 90.0% and a solid-state quantum efficiency of 87.3%, which opens an avenue for further OLEDs and bioimaging applications of nanohoops.
Добавил в систему: Сиваев Игорь Борисович

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