Interaction of rhenium hydride (eta(5)-C5Me5)ReH(Co)(NO) with fluorinated alcoholsстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 14 августа 2017 г.
Аннотация:The interaction between the fluorinated alcohols (ROH)-O-F (R-F = (CF3)(2)CH and (CF3)(3)C) and rhenium hydride (eta(5)-C5Me5)ReH(CO)(NO) in hexane and liquid freon was studied in a wide temperature range by IR and H-1 NMR methods, respectively. The formation of hydrogen-bonded complexes of two types, ReH...HORF and NO...HORF, was established. The hydride signal in the H-1 NMR spectra at 96 K splits into two signals (at delta = -7.54 and -8.87) corresponding to the free ReH and the ReH...HO complex, respectively.