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Effect of Ligand Substitution on Zero-Field Slow Magnetic Relaxation in Mononuclear Dy(III) β-Diketonate Complexes with Phenanthroline-Based Ligandsстатья
- Авторы: Gorshkov E.V., Korchagin D.V., Yureva E.A., Shilov G.V., Zhidkov M.V., Dmitriev A.I., Efimov N.N., Palii A.V., Aldoshin S.M.
- Журнал: Magnetochemistry
- Том: 8
- Номер: 11
- Год издания: 2022
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Первая страница: 151
- DOI: 10.3390/magnetochemistry8110151
- Аннотация: Herein, we report the synthesis, structure and magnetic properties of two mononuclear complexes of general formula [Dy(acac)3(L)], where L = 2,2-dimethyl-1,3-dioxolo[4,5-f][1,10] phenanthroline (1) or 1,10-phenanthroline-5,6-dione (2), and acac− = acetylacetonate anion. A distorted square-antiprismatic N2O6 environment around the central Dy(III) ion is formed by three acetylacetonate anions and a phenanthroline-type ligand. Both complexes display a single-molecule magnet (SMM) behavior at zero applied magnetic field. Modification of the peripheral part of ligands L provide substantial effects both on the magnetic relaxation barrier Ueff and on the quantum tunneling of magnetization (QTM). Ab initio quantum-chemical calculations are used to analyze the electronic structure and magnetic properties.
- Добавил в систему: Алдошин Сергей Михайлович