Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrodeстатьяИсследовательская статья
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Аннотация:The acid-catalysed protolysis of intermediates, formed either during one-electron reduction of substituted arylmercury salt (C6F5HgBr) or by the adsorption of bis(arylalkynyl)mercury compound [(C6H5CC)2Hg] on a Hg electrode has been found in low-acidic media (3 < рН < 6), whereas it was not observed in alkylmercury salt (PrnHgOAc).