Structures of germylenes and stannylenes with chelating ligands: a DFT studyстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:Geometries of 20 germylenes and 18 stannylenes based on dialkanolamines, diethylenetriamines, and related compounds were optimized by the DFT method. It was found that the most of the germylenes and stannylenes studied are more stable as dimeric structures of different types. The dimerization is possible due to either additional Ge-O(N) interactions or Ge-Ge bonding. The factors leading to the stabilzation of one or another isomer are examined.