Prospects for determination of thermodynamic and kinetic parameters of intermediates of electrode reactions by laser photoemissionстатьяИсследовательская статья
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Аннотация:The method of voltammetric time-resolved waves (TRW) based on a comparative analysis of experimental and simulated curves of photoemissionally generated intermediates was used to determine the thermodynamic and kinetic properties of the R/R– redox pairs for the benzyl PhCH2· and benzhydryl Ph2CH· radicals.