Reaction of [In(NEt2)(3)](2) with N(CH2CH2NSiMe3H)(3): Synthesis and characterization of new azaindatranes and azaindocaneстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Scopus,
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:[In(NEt2)(3)](2) and N(CH2CH2NSiMe3H)(3) react to yield monomeric azaindatrane 1, N(CH2CH2NSiMe3)(3)In, which is unstable without additional donor (e.g. pyridine), turning into dimeric azaindatrane 2, [N(CH2CH2NSiMe3)(2)(CH2CH2NH)In](2). An intermediate product of this transformation is oligomeric azaindocane 3, [N(CH2CH2NSiMe3)(2)In(CH2CH2NSiMe3)](3). The composition and structures of new compounds have been established by H-1 and C-13 NMR spectroscopy. The crystal structures of 1(.)Py, trans-2, and 3 have been determined by X-ray diffraction studies. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.