Nickel(II) and Palladium(II) Complexes with η5:κ1(N)-Coordinated Dicarbollide Ligands Containing Pendant Pyridine Group

Авторы: Семенов Дмитрий Константинович, Stogniy Marina Yu, Anufriev Sergey A., Timofeev Sergey V., Suponitsky Kyrill Yu, Sivaev Igor B.
Журнал: International Journal of Molecular Sciences
Том: 24
Номер: 20
Год издания: 2023
Издательство: MDPI
Местоположение издательства: Basel, Switzerland
Номер статьи: 15069
DOI: 10.3390/ijms242015069
Аннотация: A series of C- and B-substituted nido-carborane derivatives with a pendant pyridyl group was prepared. The synthesized compounds were used as ligands in the complexation reactions with bis(triphenylphosphine)nickel(II) and palladium(II) chlorides to give six new metallacomplexes with unusual η5:κ1(N)-coordination of the metal center. The single crystal structures of 1-(NC5H4-2′-S)-1,2-C2B10H11, 1-(NC5H4-2′-CH2S)-1,2-C2B10H11, Cs [7-(NC5H4-2′-CH2S)-7,8-C2B9H11] closo- and nido-carboranes and 3-Ph3P-3-(4(7)-NC5H4-2′-S)-closo-3,1,2-NiC2B9H10 and 3-Ph3P-3-(4(7)-NC5H4-2′-CH2S)-closo-3,1,2-NiC2B9H10 metallacarboranes were determined using single crystal X-ray diffraction.
Добавил в систему: Сиваев Игорь Борисович

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