Frontispiece: Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups

Авторы: Vatsadze Sergey Z., Loginova Yulia D., Passos Gomes Gabriel dos, Alabugin Igor V.
Журнал: Chemistry - A European Journal
Том: 23
Номер: 14
Год издания: 2017
Издательство: John Wiley & Sons Ltd.
Местоположение издательства: United Kingdom
DOI: 10.1002/chem.201781461
Аннотация: Chameleonic Behavior The traditional view of common functional groups as either donors or acceptors is challenged by stereoelectronic thinking. In the Review on page 3225 ff., S. Z. Vatsadze, I. V. Alabugin et al. discuss situations in which the donor–acceptor properties of substituents and, hence, chemical reactivity can be inverted as a function of their orientation in space with respect to the rest of a molecule. They discuss conformational, translocational and supramolecular “stereoelectronic chameleons” with focus on the situations in which the stereoelectronic “umpolung” unlocks useful ways of thinking about chemical reactivity and opens new doors for reaction design.
Добавил в систему: Вацадзе Сергей Зурабович

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