Guggenheim equation for a system of hard spheres and its generalizationстатья
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Дата последнего поиска статьи во внешних источниках: 10 апреля 2024 г.
Аннотация:In the present work, for the first time, a generalized Guggenheim equation for a system of hardspheres has been obtained based on the use of Euler’s accelerated convergence method. This equationallows for the consideration of an arbitrary number of known virial coefficients. For the metastable region,this equation is generalized to account for the asymptotic behaviour of free energy at high densities. Theobtained expression for the compressibility of the homogeneous phase of a hard sphere system describesthe data of the numerical experiment within the limits of its accuracy.