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Light‐Induced Dyotropic Rearrangement of Diarylethenes: Scope, Mechanism, and Prospectsстатья
- Авторы: Lvov Andrey G., Koffi Kouame Eric, Khusniyarov Marat M.
- Журнал: Chemistry - A European Journal
- Том: 29
- Номер: 60
- Год издания: 2023
- Издательство: John Wiley & Sons Ltd.
- Местоположение издательства: United Kingdom
- DOI: 10.1002/chem.202301480
- Аннотация: Irreversible two‐photon photorearrangement of 1,2‐diarylethenes is a unique process providing access to complex 2a<jats:sup>1</jats:sup>,5a‐dihydro‐5,6‐dithiaacenaphthylene (DDA) heterocyclic core. This reaction was serendipitously discovered during studies on photoswitchable diarylethenes and was initially considered as a highly undesired process. However, in recent years, it has been recognized as an efficient photochemical reaction, interesting by itself and as a promising synthetic method for the synthesis of challenging molecules. Herein, we discuss the state‐of‐the‐art in studies on this notable process
- Добавил в систему: KOUAME KOFFI ERIC