|
ИСТИНА |
Войти в систему Регистрация |
ИПМех РАН |
||
Influence of Diluent on Extraction Parameters of Systems for Separation Am(III) and Ln(III) Based on 1,10-Phenanthroline-2,9-Diamideстатья Исследовательская статья
- Авторы: Gerasimov Mikhail A., Matveev Petr I., Evsiunina Mariia V., Khult Enni K., Kalle Paulina, Petrov Valentine S., Lemport Pavel S., Petrov Vladimir G., Kostikova Galina V., Ustynyuk Yuri A., Nenajdenko Valentine G.
- Журнал: Molecules
- Том: 29
- Номер: 15
- Год издания: 2024
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Первая страница: 3548
- Последняя страница: 3548
- DOI: 10.3390/molecules29153548
- Аннотация: A systematic study of extraction systems for the separation of f-elements using the tetradentate N,O-donor diamide of 1,10-phenanthroline-2,9-dicarboxylic acid (L) in various molecular and ionic solvents was performed. It was demonstrated that the nature of a diluent has a significant impact on solvent extraction of Am(III) and Ln(III) and the stoichiometry of formed complexes with f-elements. The mechanism of complexation and forms of complexes in different diluents were investigated by radiometric methods, UV-vis titration, and XRD.
- Добавил в систему: Герасимов Михаил Алексеевич