Synthesis and crystal structure of a new 1D metal–organic coordination polymer with Cu<sup>2+</sup> ions based on a chiral terephthalic acid derivative synthesized for the first timeстатья
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Аннотация:The new homochiral 1D metal–organic coordination polymer {Cu[bdc-(N-MePro)H2O]·0.25H2O}n wassynthesized using 2-[(1-methyl-L-prolyl)amino]terephthalic acid, which was obtained for the first time. Theunique crystal structure of the new compound was determined using powder X-ray diffraction. Thecatalytic performance of {Cu[bdc-(N-MePro)H2O]·0.25H2O}n in the asymmetric ring opening reactions ofstyrene oxide and cyclohexene oxide with aniline was evaluated.