CHLORINE AGGREGATION IN THE SUPRAMOLECULAR STRUCTURE OF CHLOROBENZENE–о-CHLOROTOLUENE SOLUTIONSстатья
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Дата последнего поиска статьи во внешних источниках: 12 января 2015 г.
Аннотация:An analysis of the concentration dependences of the molecular light scattering parameters in
chlorobenzene–о-chlorotoluene solutions shows that the entire concentration range can be split into three
intervals with different structural features: 0-0.2 ppm, 0.2-0.9 ppm, and 0.9-1 ppm chlorobenzene. The
features are manifest in physicochemical properties such as sound velocity and excess molar volume,
adiabatic compressibility, and molar refraction. Experimental data are compared with those obtained by
molecular dynamics simulation. It is concluded that the chlorobenzene structure is determined by Cl…Cl
interactions while the structuring of liquid o-chlorotoluene and its solutions is largely determined by
intermolecular Cl…Me interactions