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Low-dimensional heterometallic assemblies involving orbitally degenerate cyanometallate and displaying slow magnetic dynamicsстатья Исследовательская статья
- Автор: Vostrikova Kira E.
- Журнал: Journal of Magnetism and Magnetic Materials
- Том: 459
- Год издания: 2018
- Издательство: Elsevier BV
- Местоположение издательства: Netherlands
- Первая страница: 71
- Последняя страница: 77
- DOI: 10.1016/j.jmmm.2017.12.022
- Аннотация: Low-dimensional (0D and 1D) molecular nanomagnets involving homoleptic cyanometallates as orbitally degenerate causing highly anisotropic magnetic exchange interactions are considered. Special attention payed to the origins of the magnetic anisotropy for two groups of metalloligands. The first includes hexacyanometallates of Fe, Ru and Os having octahedral geometry of coordination polyhedron, while the second integrates the heptacyano complexes of Mo and Re in pentagonal bipyramid coordination environment.
- Добавил в систему: Vostrikova Kira E.