First Tellurium-Containing Phthalocyanine Analogues: Strong Effect of Tellurium on Spectral, Redox and Conductivity Properties of Porphyrazines with Annulated Chalcogenodiazole Ring(sстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 8 сентября 2017 г.
Аннотация:The first tellurium-containing phthalocyanine analogues have been prepared and spectroscopically characterised: the MgII complex of tetra(1,2,5-telluradiazolo)porphyrazine and a low-symmetry tert-butyl substituted MgII tribenzoporphyrazine with one fused 1,2,5-telluradiazole ring. It was observed that the introduction of Te atom(s) reduces the energy of the Q-transition, facilitates the reduction of the macrocycle and strongly increases the conductivity of thin films.