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Dechlorination of 1,4-dichlorobenzene on unsupported nickel phosphides synthesized in situ: effect of Ni/P ratio on the catalyst activityстатья
- Авторы: Dzhabarov Eduard Gennad'evich, Petrukhina Natalya N., Kuzmin Vladislav Dmitrievich, Zakharyan Elena M.
- Журнал: Mendeleev Communications
- Том: 35
- Номер: 3
- Год издания: 2025
- Издательство: Russian Academy of Sciences
- Местоположение издательства: Russian Federation
- Первая страница: 353
- Последняя страница: 355
- DOI: 10.71267/mencom.7662
- Аннотация: The synthesis of nickel phosphides was conducted in situ during the hydrodechlorination reaction of 1,4-dichlorobenzene using either red phosphorus or triphenylphosphine as a starting reactant to produce the phosphides. At Ni/P ratio of 1 : 0.5, the most active nickel phosphide phase, Ni2P, was observed. An increase in phosphorus loading resulted in reducing the degree of dechlorination.
- Добавил в систему: Захарян Елена Михайловна