Kinetic criteria of glass-formation, pressure dependence of the glass-transition temperature, and the Prigogine–Defay ratio

Schmelzer Jürn, W.P.; Tropin, T.V.

Авторы: Schmelzer Jürn W.P., Tropin Timur V.
Журнал: Journal of Non-Crystalline Solids
Том: 407
Год издания: 2015
Издательство: Elsevier BV
Местоположение издательства: Netherlands
Первая страница: 170
Последняя страница: 178
DOI: 10.1016/j.jnoncrysol.2014.07.049
Аннотация: An analysis of some current topics of discussion in the theoretical modeling of the glass transition and of glass properties is given. In the first part, a general model-independent kinetic criterion of glass-formation is formulated. Its interrelation with other attempts of formulation of such criteria is discussed and some consequences not studied so far in detail are analyzed. It is shown that the value of the glass transition temperature depends not only on system properties and rates of change of external control parameters but, as a rule, also on the property of the system measured for its specification. In addition, systems described by several structural orderparameters may exhibit multiple glass transitions. The respective glass transition temperatures are shown to depend on the spectrumof relaxation times of the respective structural order-parameter and the degree of deviation of the systemfromthe thermodynamic equilibriumstate. Employing mentioned kinetic criteria, further on general equations for the pressure dependence of the glass transition temperature and the value of the viscosity at the glass transition temperature in dependence on cooling rate are formulated. In the second part, existing different approaches to the theoretical determination of the Prigogine–Defay (PD) ratio in glass transition are critically reviewed. As shown, following the kinetic approach to the determination of the glass transition temperature Tg, the analysis of the pressure dependence of Tg does not lead to any generally valid predictions for the value of the PD-ratio. It is demonstrated further that some recent attempts to question it do not affect the basic result of earlier analysis (J. W. P. Schmelzer and I. Gutzow, J. Chem. Phys. 125, 184511/1-11 (2006)) concerning the possibility to predict theoretically values of the PD-ratio larger than onewhen only one structural order-parameter is employed to describe kinetic freeze-in at glass transition.
Добавил в систему: Тропин Тимур Васильевич

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Kinetic criteria of glass-formation, pressure dependence of the glass-transition temperature, and the Prigogine–Defay ratioстатья