Conjugates of boron clusters with derivatives of natural chlorin and bacteriochlorinстатья
Статья опубликована в высокорейтинговом журнале
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Дата последнего поиска статьи во внешних источниках: 9 ноября 2017 г.
Аннотация:Conjugates of bacteriochlorin p and chlorin e6 with cobalt bis(dicarbollide) anion [3,3’-Co(1,2-C2B9H11)2]- were synthesized using different synthetic approaches.The boronated bacteriochlorin
p was prepared by reaction of bacteriochlorin N-aminocycloimide with bis(dicarbollide)-based
carboxylic acid.The boronated chlorin e6 conjugates were obtained by both ‘‘click reaction’’ of
containing alkyne group chlorine with azide derivative of cobaltacarborane and reaction of chorin-
based amines with cyclic oxonium derivative of cobaltbis(dicarbollide).