REDOX KINETICS OF METAL-COMPLEXES IN NON-AQUEOUS SOLUTIONS .4. OXIDATION OF IRON(II) SOLVATES BY IRON(III) IN ACETONITRILE AND PROPANEDIOL-1,2-CARBONATEстатья
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Аннотация:The oxidation of iron(U) solvates by Fe(phen)p in
acetonitrile (An) and propanediolcarbonate (PDC)
proceeds via the same reaction scheme as the reduction
of iron(III) solvates by Fe(tetramethylphen)::
Solutions of iron(H) solvates in these solvents contain
not only FeLg, but also complexes of lower coordination
number. The lower the coordination
number the faster the oxidation of the iron
species. In An an intermediate is formed between the
pentacoordinated solvate and Fe(phen)? which is
obviously stabilized by the solvent.