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Kinetics and mechanism of catalytic hydroxylation of phenol by hydrogen peroxide .4. Modeling of the stage of dihydroxybenzene oxidationстатья
Информация о цитировании статьи получена из
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Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 23 ноября 2017 г.
- Авторы: Litvintsev IY, Timofeev SV, Sapunov VN
- Журнал: Kinetics and Catalysis
- Том: 37
- Номер: 2
- Год издания: 1996
- Издательство: Maik Nauka/Interperiodica Publishing
- Местоположение издательства: Russian Federation
- Первая страница: 193
- Последняя страница: 201
- Аннотация: The kinetics of individual and combined peroxide oxidation of target products of the catalytic hydroxylation of phenol to dihydroxybenzenes, i.e., pyrocatechol and hydroquinone, in the presence of homogeneous catalysts (iron sulfate and its complex with pyrocatechol:) is studied under conditions typical of this process. The series of one-factor experiments results in the development of mathematical models that adequately describe the principles observed. The possible mechanism of individual and combined oxidation of dihydroxybenzenes is discussed.
- Добавил в систему: Сапунов Валентин Николаевич