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STUDY OF THE KINETICS OF THE CATALYTIC DECOMPOSITION OF ETHYLBENZENE HYDROPEROXIDE BY THE INITIAL RATES METHODстатья
Информация о цитировании статьи получена из
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Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 23 ноября 2017 г.
- Авторы: AKHMEDYANOVA RA, LITVINTSEV IY, MONAYENKOV AY, SAPUNOV VN
- Журнал: Petroleum Chemistry
- Том: 34
- Номер: 5
- Год издания: 1994
- Издательство: Pleiades Publishing, Ltd
- Местоположение издательства: Road Town, United Kingdom
- Первая страница: 413
- Последняя страница: 420
- Аннотация: An investigation has been made of the kinetic relationships governing the decomposition of ethylbenzene hydroperoxide (EBHP) in the presence of a complex molybdenum catalyst (KMK). Data obtained by processing the curves of product accumulation and EBHP consumption by the initial rates method are given. With account taken of published data and the composition of the products, it is concluded that, at the initial moment, there are two routes by which EBHP decomposition occurs. The presence of molybdenum in low states of oxidation in the KMK has been demonstrated by spectral methods.
- Добавил в систему: Сапунов Валентин Николаевич