|
ИСТИНА |
Войти в систему Регистрация |
ИПМех РАН |
||
Investigation of Ion-Molecular Reactions of Nucleogenic Phenyl Cations with 1,4-Diazine Derivativesстатья
- Авторы: Shchepina N.E., Avrorin V.V., Badun G.A., Vasyanin A.N., Shurov S.N., Agafonova I.M.
- Журнал: Chemistry of Heterocyclic Compounds
- Год издания: 2015
- Издательство: Kluwer Academic/Plenum Publishers
- Местоположение издательства: United States
- DOI: 10.1007/s10593-014-1629-6
- Аннотация: The use of nuclear-chemical synthesis, based on the generation of free nucleogenic phenyl cations, allowed for the direct phenylation of the nitrogen atom in 1,4-diazines. The presence of two methyl substituents in the quinoxaline substrate leads to a marked increase of diazine salt radiochemical yield. On the basis of quantum-chemical calculations the possibility of synthesizing 2,3-dimethyl-1,4-di-phenylquinoxalinium dication is proposed.
- Добавил в систему: Бадун Геннадий Александрович