Study of lithium complexes with benzo-15-crown-5 ether by X-ray diffraction and IR spectroscopyстатья
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Дата последнего поиска статьи во внешних источниках: 2 февраля 2018 г.
Аннотация:The complex formation of lithium with benzo-15-crown-5 (B15C5) was investigated. The com- plexes LiB15C5H OX, where X = Cl− (1), I− (2), ClO− (3), NO− (5), and LiBF B15C5 (4) were synthesized
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and studied by IR spectroscopy. Complexes 1–4 were examined by X-ray diffraction. According to IR spec- troscopy data, the crown ether conformation changes upon dissolution. The interaction of the extracted com- plex with the solvent was identified.