Heck Reaction of Electronically Diverse Tertiary Alkyl Halidesстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 7 марта 2018 г.
Аннотация:The efficient Pd-catalyzed Heck reaction of diverse tertiary alkyl halides
with alkenes has been developed. Unactivated tertiary alkyl halides efficiently react at
room temperature under visible light irradiation with no exogenous photosensitizers
required. For activated tertiary alkyl halides, the same catalytic system works well
without light. These methods offer a general access to electronically diverse alkenes
possessing quaternary and functionalized tertiary allylic carbon centers. The substituents
at these centers include alkyl-, carbalkoxy-, tosyl-, phosphonyl-, and boronate groups. It
was also shown that the end-game mechanism of this transformation may vary
depending on the type of the substrates used.