Аннотация:Volume 45 in the highly successful series Handbook of Porphyrin Science presents three very informative chapters of significant topical interest to researchers in the broad field of porphyrin science. The first chapter (Chapter 215) systematically describes in great detail the many synthetic methods utilized for the preparation of both metal-free and metallo-phthalocyanines.
The following sections are included:
List of Abbreviations
Introduction
Representative Synthesis Methods
Phthalic Anhydride, Phthalimide, and Phthalamide (Wyler) Methods
Phthalonitrile Method
1,3-Diiminoisoindoline Method
Synthesis of Metal-Free Phthalocyanines
Phthalonitrile Methods
1,3-Diiminoisoindoline Method
Demetalation
Synthesis of Metallophthalocyanines
Organic Solvent-Soluble Metallophthalocyanines
Group 1: Li2Pc, Na2Pc, K2Pc, Rb2Pc, and Cs2Pc
Group 2: BePc, MgPc, CaPc, and BaPc
Group 3: ScPc, ScPc2, YPc, YPc2, and YPc3
Complexes of the Lanthanide and Actinide Elements
Group 4: TiPc, TiPc2, ZrPc, ZrPc2, HfPc, and HfPc2
Group 5: VPc, NbPc, and TaPc
Group 6: CrPc, MoPc, and WPc
Group 7: MnPc, TcPc, and RePc
Group 8: FePc, RuPc, and OsPc
Group 9: CoPc, RhPc, and IrPc
Group 10: NiPc, PdPc, and PtPc
Group 11: CuPc, AgPc, and AuPc
Group 12: ZnPc, CdPc, and HgPc
Group 13: B-subPc, AlPc, GaPc, InPc, and TlPc
Group 14: SiPc, GePc, SnPc, SnPc2, and PdPc
Group 15: PPc, AsPc, SbPc, BiPc, BiPc2, and Bi2Pc3
Water-Soluble Metallophthalocyanines
Anionic Water-Soluble Phthalocyanines
Sulfonyl Group
Carboxyl Group
Cationic Water-Soluble Phthalocyanines
Quaternary Amine
Pyridine
Non-Ionic Water-Soluble Phthalocyanines
Conclusions
Acknowledgments
References
