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TARGETS IN HETEROCYCLIC SYSTEMS: CONSTRUCTION OF 1,4,6,10-TETRAAZAADAMANTANES VIA INTRAMOLECULAR OXIME/HYDRAZONE CYCLOTRIMERIZATION APPROACHкнига
- Авторы: Semakin Artem N., Sukhorukov Alexey Yu
- Год издания: 2017
- Место издания: Italian Society of Chemistry Roma, Italy
- Объём: 16 страниц (1,0 печатных листов)
- Монография
- DOI: 10.17374/targets.2018.21.82
- Аннотация: The account is focused on the synthesis of 1,4,6,10-tetraazaadamantanes, a new class of heterocage scaffolds isomeric to urotropine (methenamine). The suggested strategy to the assembly of 1,4,6,10-tetraazaadamantane cage employs an intramolecular [2+2+2] cyclotrimerization reaction in a suitable tris-oxime or tris-hydrazone precursor. Various 1,4,6,10-tetraazaadamantane derivatives including unsymmetrically substituted ones are accessible by this route.
- Добавил в систему: Сухоруков Алексей Юрьевич