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Arsenic evolution as a tool for understanding formation of pyritic gold oresстатья
Статья опубликована в высокорейтинговом журнале
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 21 мая 2019 г.
- Авторы: Xing Y., Brugger J., Tomkins A., Shvarov Y.
- Журнал: Geology
- Том: 47
- Номер: 4
- Год издания: 2019
- Издательство: Geological Society of America
- Местоположение издательства: United States
- Первая страница: 335
- Последняя страница: 338
- DOI: 10.1130/G45708.1
- Аннотация: Arsenic (As) and gold (Au) are closely associated in many gold deposits, both being hosted in Fe-sulfide minerals (pyrite, marcasite, and arsenopyrite), partly because As geochemistry controls Au accumulation. Yet, the partitioning behavior of As between pyrite, arsenopyrite, and hydrothermal fluids remains poorly understood. Here, we introduce solid-solution models for As in pyrite and As in arsenopyrite into a thermochemical model of fluid-rock interaction, and use it to evaluate the effects of temperature, redox state, and fluid-flow dynamics on As—and Au by association—partitioning. We find that As concentrations in pyrite decrease with increasing temperature, despite the widening of the solid-solution composition range. This is related to the preferential partitioning of As into fluids at higher temperatures. Simulations of infiltration of rock-buffered H2O-CO2-As fluids into low-As pyrite (As:S = 0.01) ores reveal a continuous enrichment of As in pyrite with increasing fluid:rock ratio. The modeling suggests that upgrading of early-formed low-grade ores by multistage hydrothermal events can generate large gold deposits. In this scenario, an anomalously Au-rich fluid is not needed, but instead, prolonged fluid-rock interaction enriches pyrite in As, which promotes gold sequestration.
- Добавил в систему: Шваров Юрий Всеволодович
Прикрепленные файлы
| № | Имя | Описание | Имя файла | Размер | Добавлен |
|---|---|---|---|---|---|
| 1. | Полный текст | 2019Xingal_Geology.pdf | 511,0 КБ | 14 апреля 2019 [YuriShvarov] | |
| 2. | Результаты экспериментов | приложение к статье | 2019bXingal_Geology.pdf | 742,7 КБ | 30 августа 2019 [YuriShvarov] |